Product ID:HT 424 THIXOTROPIC PASTE, PART A
MSDS Date:07/04/1992
FSC:8040
NIIN:01-213-0565
Kit Part:Y
MSDS Number: BPHTH

AMERICAN CYANAMID COMPANY

ONE CYANAMID PLAZA
WAYNE, NJ 07470
US

Emergency Phone: 201-831-2000,1-800-424-9300CHEMTREC

Info Phone: 201-831-2000,410-939-8188

Preparer: MARVIN A. FRIEDMAN

Cage: 70361

AMERICAN CYANAMID CO

CLIFTON, NJ 07015 US

Telephone: 973-683-2000

Cage: 70361

FORMALDEHYDE (SARA III). LD50 RAT ORAL 500-800 MG/KG;RABBIT

CAS: 50-00-0

RTECS: LP8925000

Fraction By Weight: <0.91%

OSHA PEL SEE 1910.1048

ACGIH TLV: C 0.3 PPM; A2; 9293

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

PHENOL (SARA III). LD50 RAT ORAL 0.414 G/KG.LD50 RABBIT

CAS: 108-95-2

RTECS: SJ3327000

Fraction By Weight: <5.46%

OSHA PEL 5 PPM,SKIN

ACGIH TLV: 5 PPM,SKIN

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

COPPER-8 QUINOLINOLATE. LD50 RAT ORAL >17.0 G/KG,RABBIT

CAS: 10380-28-6

RTECS: VC5250000

Fraction By Weight: 0.80%

OSHA PEL NOT KNOWN

ACGIH TLV: NOT KNOWN

SILICA,AMORPHOUS. LD50 RAT ORAL >7.5 G/KG.LC50 RAT INHAL

CAS: 7631-86-9

Fraction By Weight: 3.20%

OSHA PEL 6 MG/M3 TOTAL DUST

ACGIH TLV: 10 MG/M3 TOTAL DUST

LD50 LC50 Mixture:LD50 RAT ORAL 3200 MG/KG,RABBIT(SEE SUP)
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:INHAL OF DUSTS & MISTS OF CU SALTS CAN
RESULT IN ULCERATION W/ PERFORATION OF NASAL SEPTUM.INGEST MAY
CAUSE HEMORR GASTRITIS & DIARR.CHRONIC EXP MAY RESULT IN ANEMIA,
ITCHING ECZEMA, CONJ OR ULCERATIO N OF CORNEA. PHENOL IS ABSORBED
THROUGHSKIN/DIGESTIVE TRACT.PRLNG OVEREXP CAN CAUSE HEART & NERVOUS
(SEE SUP)
Explanation of Carcinogenicity:FORMALDEHYDE:SUSP HUM CARC/KNOWN ANIM
CARC (NTP,1991).LIM EVID FOR CARC IN HUM;SUFF EVID FOR CARC IN ANIM
(SEE SUPP)
Effects of Overexposure:EYES:IRRITATION OR BURNS (PHENOL).IRRITATION
(FORMALDEHYDE). SKIN:BURNS (PHENOL).IRRITATION (FORMALDEHYDE).
INGESTION:CU SALTS MAY CAUSE SALIVATION,NAUSEA,VOMITING,GASTRIC
PAIN.PHENOL MAY CAUSE MUC ME MB BURNS. INHAL:CU DUSTS/MISTS CAN
CAUSE NASAL MUC MEMB IRRIT.FORMALDEHYDE VAPOR CAUSE RESP TRACT
IRRIT.
Medical Cond Aggravated by Exposure:NOT KNOWN

First Aid:EYES:IN CASE OF EYE CONTACT,IMMEDIATELY IRRIGATE WITH PLENTY
OF WATER FOR AT LEAST 15 MINUTES. SKIN:IN CASE OF CONTACT,WASH
AFFECTED AREAS OF SKIN WITH SOAP AND WATER.

Extinguishing Media:USE WATER,CARBON DIOXIDE,OR DRY CHEMICAL TO
EXTINGUISH FIRES.
Fire Fighting Procedures:WEAR SELF-CONTAINED,POSITIVE PRESSURE
BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:THERMAL DECOMPOSITION OR COMBUSTION MAY
PRODUCE CARBON MONOXIDE,CARBON DIOXIDE,AMMONIA AND/OR OXIDES OF
NITROGEN.

Spill Release Procedures:EXPOS LEVEL UNKNOWN-WEAR NIOSH APPRVD,POS
PRESS,SELF-CONTAINED RESP.EXPOS LEVEL KNOWN-WEAR NIOSH APPRVD RESP
SUITBLE FOR LEVEL OF EXPOS.WEAR SAME PROT CLTHG/EQUIP AS IN EXPOS
CONTROL METH.SWEEP UP SPI LL.PLACE IN WASTE DISP CONTR.FLUSH AREAW/
WATER.
Neutralizing Agent:NOT KNOWN

Handling and Storage Precautions:FOOD,BEVERAGES AND TOBACCO PRODUCTS
SHOULD NOT BE CARRIED,STORED OR CONSUMED WHEN THIS MATERIAL IS IN
USE.
Other Precautions:STORE STREET CLOTHING SEPARATE FROM WORK CLOTHING AND
PROTECTIVE EQUIPMENT.WORK CLOTHING AND SHOES SHOULD NOT BE TAKEN
HOME.AVOID CONTACT WITH EYES,SKIN, AND CLOTHING.

Respiratory Protection:IF EXPOSURES ARE BELOW THE PEL,NO RESP PROT IS
REQ.WHERE EXPOSURES EXCEED THE PEL,USE RESP APPROVED BY NIOSH FOR
MATL & LEVEL OF EXPOSURE.A FULL FACEPIECE WILL PROVIDE EYE AND FACE
PROTECTION.CUTTING, GRINDING OR SANDING OF PARTS (SEE SUPP)
Ventilation:IF NOT USED IN CLSD SYS,PROVIDE GOOD ENCLOSURE & LOC
EXHAUST VENT TO CONTROL EXPOS IF SPRAYING/CURING AT ELEVATED TEMPS.
Protective Gloves:IMPERVIOUS GLOVES & BARRIER CREAMS.
Eye Protection:CHEMICAL SPLASH GOGGLES OR FACESHIELD.
Other Protective Equipment:EYEWASH,SAFETY SHOWER.PROTECTIVE SUIT MAY BE
REQUIRED.APRON,WORKPANTS,LONG-SLEEVED WORK SHIRT OR DISP COVERALLS
RECOMND.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.BEFORE
EATING/DRINKING/SMKNG,WASH FACE & HANDS W/SOAP & WATER.SHOWER RECOM
AFTER SHIFT.
Supplemental Safety and Health
LD50/LC50 MIX:DERMAL 1900 MG/KG;LC50 RAT INHAL 18 MG/4 HR.EXPLAN OF
CARCIN:(IARC,1987).OSHA:KNOWN HUM CARCIN (OSHA,1985).ACGIH
A2=SUSPECT HUM CARCIN (1992).HLTH HAZ:SYS EFFECTS.RPTD SKIN EXP TO
>2% FO RMALDEHYDE SOLUTION CAUSED ALLERGIC SKIN RXN.RESP
PROT:FABRICATED AFTER CURING MAY CREATE RESPIRABLE DUST PARTICLES.

Spec Gravity:1.0 (WATER=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:BROWNISH-GREEN PASTE,SLIGHT PHENOLIC ODOR.
Percent Volatiles by Volume:20%WT

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:CARBON MONOXIDE,CARBON DIOXIDE,AMMONIA
AND/OR OXIDES OF NITROGEN.
Conditions to Avoid Polymerization:DO NOT HEAT MATERIAL ABOVE
100F,37.8C.

Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE W/ FEDERAL,STATE
& LOCAL REGS.COORDINATION W/ SUPPORTING INSTALLATION &/OR MACOM
ENVIRONMENTAL COORDINATION PRIOR TO DISP IS RECOM TO DETERMINE
APPROPRIATE DISPOSAL METH ODS .

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.